This video offers a precise and accessible explanation of thermodynamic principles, making complex energy measurements easy to grasp for students. It effectively bridges the gap between abstract theory and practical chemical analysis.
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The terrifying energy inside a bomb calorimeter #science #chemistry #shorts追加:
Internal energy.
When a change occurs in a chemical system, to know how much energy is released or absorbed, we need a quantity representing total energy of that system.
It is the sum total of chemical, [music] electrical, mechanical, and all other energies of that system.
>> [music] >> That quantity is called internal energy.
It is represented by symbol U.
Bomb calorimeter delta U measurements.
>> [music] >> In chemical reactions, heat absorbed at constant volume is measured in a bomb calorimeter.
Bomb calorimeter is placed in a water bath.
>> [music] >> This whole arrangement is called calorimeter.
Bomb calorimeter is thermally insulated.
Therefore, there is [music] no heat exchange from calorimeter to surroundings.
During reaction, calorimeter is kept completely closed. [music] Therefore, there is no change in its volume.
At constant volume, delta [music] V is equal to zero.
W is equal to P delta V. That is equal to zero. That means no work is done.
Using the increase in temperature [music] of calorimeter due to reaction, the heat evolved can be calculated from mass of calorimeter [music] and its heat capacity values through this equation.
Q is [music] equal to C delta T.
Delta H measurements.
Since atmospheric pressure remains constant, the heat change produced by reaction [music] in calorimeter can be considered as measured at constant pressure.
QP is equal to delta H.
Therefore, heat change measured at constant pressure >> [music] >> becomes heat of reaction or enthalpy of reaction, delta small r H.
Heat is given from system to surroundings. [music] Therefore, QP is negative and delta small r H is negative.
If heat is absorbed, [music] QP and delta RH is positive.
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