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AB Tutorial
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Nitriles (RCN) undergo reduction with sodium in alcoholic medium to produce primary amines (CH2NH2), while partial hydrolysis using alkaline hydrogen peroxide or concentrated acid under low temperature yields aldehydes, and complete hydrolysis with strong mineral acids produces carboxylic acids; isocyanides (RNC) reduce to secondary amines, and alkyl halides (RX) undergo nucleophilic substitution with various nucleophiles including silver nitrate (yielding alkyl nitrites), sodium alkoxide (Williamson synthesis for ethers), sodium hydrosulfide (yielding thiols), and sodium thiolate (yielding thioethers).

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