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12th Chemistry II Formation of haloalkane and Physical properties of haloalkane II Pandit sir

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133 views14likes53:25PHYSICSBIHAROriginal Release: 2026-07-22

Haloalkanes are formed through three main halogen exchange reactions: the Swart reaction (using AgF to produce alkyl fluorides), the Finkelstein reaction (using NaI in acetone to produce alkyl iodides), and the Hunsdiecker method (using silver carboxylate with Br2 in CCl4 to produce alkyl bromides). The physical properties of haloalkanes include: physical state varies with carbon chain length (C1-C2 are gases, C3-C18 are liquids, above C18 are solids); they are slightly soluble in water but highly soluble in organic solvents; density is greater than hydrocarbons due to dipole-dipole forces; melting and boiling points increase with molecular mass; and dipole moment depends on molecular symmetry (e.g., CCl4 has zero dipole moment due to symmetry).