study of pharmacy with me Arcanics is live!

[00:00:11]I will hold the phone in the mobile stand. So, keep watching.

[00:00:33]Yeah, yeah, yeah.

[00:00:38]Is that it?

[00:00:49]Oh boy.

[00:01:20]Organic chemistry.

[00:01:23]Practical exam.

[00:01:25]Practical exam.

[00:01:44]Nightmare come.

[00:02:01]Hydro hydraysis of rignar reagent reagent in R Mg X H2 H alky hydrogen sorry alkan plus magnesium hydroxide formed first by vector That is why alkyle helide react with the magnesium metal vigorously.

[00:02:37]Reaction take place in a pressure of either to give to give alky magnesium all which on react with water to give an alkan normal alkan. Coupling of alky with organo metallic compound.

[00:03:14]injector.

[00:03:30]Okay.

[00:03:40]lithium copper coupled with a second to give reaction of alkanes.

[00:04:04]No alkans. Huh?

[00:04:17]Hi. Hi. Bye.

[00:04:32]to hogenation of alken. Electrophilic alipic substitution reaction.

[00:04:39]Electropilic substitution reaction.

[00:04:43]Electable.

[00:05:16]with the presence of a high heat and pressure.

[00:05:29]Hello. Hello. Hello.

[00:05:32]Hello. Hi.

[00:05:40]H under the influence of heat of a light the molecule of alken react with hogen to form alky h the reactivity of hogen is different and order of reactivity chlorine chlorine broine acid reaction direct Example, substitution reaction directly elect mechanism Step one reactivity.

[00:07:22]CL3 about CH2 CL2 Control of reaction at the start of The reaction only methane molecule available to react with the chlorine. But after first step of chlorination methile chloride form which is also compacts with methane to react with CL2. Yes methyl chloride reactable methane.

[00:07:49]In study of a methane CL2 may react with a methile chloride to form methylene chloride. And at the end of a reaction we get a mixture of four products concurrency carbon tetrachloride chloroform dchloro methane or monocchloromthane or methane component.

[00:08:13]So in the case at the end of a first step unreacted methane is in a higher concentration. So chlorine is more likely to attach methane than methile chloride.

[00:08:30]Free radical type of reaction. Free radical type of reaction.

[00:08:45]Chain initiation propagation.

[00:09:11]By the use of energetic light, a chlorine molecule dissociate in two highly reactive chlorine for oh sorry free radical [clears throat] chain propagation.

[00:09:28]free radical.

[00:09:46]Hi. Hi. Hi. Bye. Hi.

[00:09:51]Here the collision of methane with a chlorine radical is a probable and productive.

[00:10:10]or final stepmination.

[00:10:15]Termin.

[00:10:44]compositions possible radical reaction.

[00:10:56]So control of reaction inhibitors. When the comp when the compound used in a very small amount to control the reaction it is called inhibitor.

[00:11:11]In this reaction a methile radical have a ability to bind with a chloride radical. Methile radical and hydrogen radical but methile chloride form only.

[00:11:21]When methile radical react with chlorine radical.

[00:11:26]So here to control the reaction done by adding a small amount of active oxygen.

[00:11:33]Yes.

[00:11:38]So here this auto reacts with a partial molecule of methile chloride to form a stable compound like methoxides. Okay.

[00:11:51]So overall concentration of methile chlor sorry methile radical get reduced.

[00:11:56]Therefore it's radially rad readily available to react with chloride radical. Okay. Fine.

[00:12:12]Say hi.

[00:12:43]already hybridiz.

[00:12:55]rules.

[00:12:58]I UPSC Indian Union Indian Union 9 International Union for Pure and Applied Chemistry.

[00:13:29]Isomer geometric isome when the isomer is a form due to presence of double bond and the rotation.

[00:13:42]of this double bond is a restrictor.

[00:13:49]component opposite side compound side on the same side when a similar groups are bound to a same side of double bond the alken is considered as This is isomer.

[00:14:20]When similar group are found to the opposite side of the double bond, it is called trans isomer. H double bond E or Z isomer. E when attachment of a different element with a carbon double bond carbon assign the group on the basis of a higher priority by considering the atomic number from highest to lowest to give name of molecule. If the higher priority group on the same side same side it is called Z isomer and if it is the opposite side then it is a E isomer.

[00:15:08]Preparation of alken.

[00:15:23]diagenation of alken alkine is hydrogenation of alkine it's made up of alken elimination type of reaction elimination type of reaction or catalyst reduction of reaction.

[00:16:29]Hydrogenation of alkyes. Hydrogenation of alkine hydrogen present [clears throat] direct.

[00:16:46]Linder berium catalyst.

[00:17:13]said hi. Bye. Hi and R C triple bond.

[00:17:32]Nickel or hydrogen catalyst double bond opposite side.

[00:17:59]Main J reaction elimination reaction.

[00:18:05]The introduction of carbon double bond carbon into a molecule having a single bond and must invol remove of atom or group from an adjacent carbon. It is called elimination reaction.

[00:18:26]component.

[00:18:46]E2 reaction. E2 reaction.

[00:18:52]E2 reaction. Biomolecular type of reaction.

[00:18:56]Two molecular work.

[00:19:02]Second order and E2 difference H to E2. E2 means depend. E2 means single step.

[00:19:40]without any intermediate transition.

[00:19:53]This reaction done by the use of alky helite in which elimination of a hydrogen and a hogen from alkyle helide to form a alkine carbon carbon HX alky Strong transition.

[00:20:31]Intermediate step. Transition step.

[00:20:46]Follow single step elimination rate of reaction.

[00:20:58]Reactivity. Order of reactivity.

[00:21:01]3° most.

[00:21:13]When alkalhalide re with concentrated alcohol, a strong base to form alken, KX and water. One and two elimination of HX follow E2 mechanism.

[00:21:39]Here the base is required to extract a proton from beta carbon and it must leave its electron pair behind.

[00:22:12]O minus direct water.

[00:22:19]This electron pair is available to form a pi bond between the two carbon atom.

[00:22:26]Hogen leave from the molecule as a allied ion by taking lone pair of electron with itself.

[00:22:34]Lone pair of electron both the anti- elimination and sign elimination are possible depending upon the position of hydrogen and living group reactivity orientation 3° 2° 1°ree Yeah.

[00:23:04]Maximum branch double bond reactivity.

[00:23:12]The overall reactivity of E2 elimination depend upon the type of substrate substrate and the reactivity of order 3° 2° 1°.

[00:23:24]32 reaction the branching branching at alpha carbon give a greater number of beta hydrogen for react attack by basis for 3° carbon it gives amounts a more stabilized product as for rule likes men Christina Raina 2022 said hi. Hi Christina Raina. Hello. Hello Heba. Hi message.

[00:24:22]Oh, thank you for the comments, guys.

[00:24:30]orientation smokes.

[00:24:32]In a dehydrohalogenation, the preferred product is the alken that has the greater number of alky group attached with a double bond carbon dead. According to this rule, the elimination in which a formation of a more stable alken is a preferred most is the hydrohenogenation of a secbutile bromide. Sacile broile.

[00:25:37]The two butin is more stable than one butane because the greater number of alkaline group attached to a double bond and carbon. So here it two butile to alky group attached in one butane only one alk attached.

[00:25:59]E1 elimination E1 elimination.

[00:26:06]Oh, live stream.

[00:26:23]Elimination. Elimination.

[00:26:28]Hello. Hello. Hello.

[00:26:31]Elimination. Dehydration of alcohol.

[00:26:34]Dehydration of alcohol.

[00:26:47]Even reaction rate of reaction or safe or continue your reaction.

[00:27:17]The dehydration of alcohol take place by heating it with alcohol in a presence of H2SO4. Strong acid polyphosphoric acid both are acidic catalyst or bypassing the alcoholic vapor over the layer of aluminium.

[00:27:39]That's true.

[00:27:44]The step is acidbased reaction between the alcohol and a catalyzing acid to form a protonated alcohol. Due to formation of carocetine the conjugated base of an acid abstract the proton to form a stable alken and this step consider the first step. Rate of reaction is equal to K R O H zero. First order kinetics.

[00:28:15]Yes. First order kinetics.

[00:28:43]The order of reactivity it is a depending on rate of formation of carocetine and its stability. So first carboation more stable than secondary carocetine rearrangement of even elimination. Huh?

[00:28:59]Why carbo rearrangement?

[00:29:06]The rearrangement it is the process of a stabilization in which the least stable caroclation converts into highly stable species by migration of one or more species from first position to other position.

[00:29:30]Orientation.

[00:29:32]Orientation.

[00:29:51]Orientation.

[00:29:53]Orientation. Yes. When more than one alken is a formed by dehydration of alcohol the more highly branched alken molecule will form as in a major concentration and it's considered as preferred product difference between E1 and E2 reactions please comment section to Difference between E1 and E2 reaction. Elimination reaction one or comction comment section. in the hole again.

[00:31:26]organic chemistry.

[00:31:53]yellowy pharmacy or science student Okay.

[00:32:30]Uh E1 elimination. Even elimination is elimination of alcohol to form aline or it will elimination elimination of hogen to form alder or reaction incomplete. First step is depend on catalyst. Yes.

[00:33:24]rate of reaction radiation. Oh, radiation reaction reaction of alken.

[00:33:44]Oh, Electrophilic addition reaction.

[00:34:48]Positive positive charge ion is Anti-reaction.

[00:35:55]Electrphilic addition reaction.

[00:35:59]Why alken under goes electrofphilic addition reaction performed?

[00:36:08]All alkenes having one or more double bond means one sigma and one pi bond. So here the so here the addition of reaction result in the conservation of one sigma conversion of one sigma and one pi bond into two sigma.

[00:36:29]Reason shows the pi bond result from or overlapping of p electron. The pi electron lie above and below the plan of sorry plane of double bond. So this electron cloud easily available for electropillic for a attack result.

[00:37:23]Electrphilic addition reaction.

[00:37:27]Electrphilic addition reaction.

[00:37:30]Okay. Electrphilic nucleophilic three radical nucleophilic carbon double bond carbon which carbon double bond oxygen which th subscriber. But 31 reaction. Carbon double bond carbon Yeah.

[00:39:00]100 subscriber.

[00:39:14]The B electron of alken attacks on a positive species of B agent to form a carocetine. The energy is required to form a bond in a carocetine. It is available from the liberated energy from breaking of fiber.

[00:39:34]Step two.

[00:39:37]First step for the carocetine attacks on a negative species form stable addition product.

[00:40:20]The overall reactivity of alken towards electrofilic addition depends upon a substitution available on a subtract electron withdrawing group. electron withdrawing group plus caroxyic acid esester alihide amide or ammonia ion electron withdrawing group at a carbon double bond carbon decreased Increase the reactivity by lowering electron density at carbon double bond carbon and by the decrease stability of carocetine form in state one electron donating group electron sulfur hydro uh sulfur hydride C3 electron donating groups at a carbon double bond carbon increase the reactivity by stabilizing carboation form in a step one orientation. The orientation it is given by a maronei when and unsymmetrical reagent is added to carbon double bond carbon of unsymmetrically subract for electroinic. The positive portion of reagent goes to the side of a double bond or bond that contains more number of hydrogen.

[00:43:03]Then one symmetrical reagent is added to carbon bubble bond carbon or unsymmetrical substrate.

[00:43:13]For electroic attack the positive portion of reagent positive portion of reagent goes to the side of that contains more number of hydrogen.

[00:43:44]Nucleophilic addition reaction.

[00:43:47]Nucleophilic addition reaction.

[00:43:53]radical type of reaction.

[00:44:07]Step one, reagent YW + the formation of free radical done by passing UV light or peroxide.

[00:44:21]Step two, the free radical attack to carbon double bond carbon to form a new free radical.

[00:44:31]Step three, antimaronical reaction peroxide effect.

[00:44:44]When the reagent attacks on unsymmetrical alken on a free radical addition the hydrogen free radical attack on doubly bonded carbon when least number of hydrogen present the product were formed it is a called antimaronic Hold up.

[00:45:50]Heat up here.

[00:46:27]This is cool.

[00:46:49]The addition of HBr into alkine in the presence of peroxide such as short Okay.

[00:47:14]So, All right.

[00:48:08]Change case.

[00:48:14]Okay. SBI second yellow.

[00:48:44]started 10 to That Start.

[00:49:46]is known as peroxide effect.

[00:50:07]You can't even make me up.

[00:50:27]Hydro oxidation.

[00:50:50]B3 hydrate and attack on the car is kine.

[00:51:03]and form ethile bond which on oxidation by S2 to give More on the old night.

[00:52:26]acid and hydrate for reaction carbon carbon.

[00:52:35]Okay.

[00:53:20]Heat.

[00:53:31]Heat.

[00:53:52]12600 subscriber.

[00:54:35]Mom.

[00:54:53]Maybe controls.

[00:55:15]Learn about command settings.

[00:55:19]Okay.

[00:55:36]Not close.

[00:56:08]Focus.

[00:56:22]Monogonite is quite unstable. It is the same decomposition to give a fragment of ozone egg. This fragment where we arranged to give orders by say that shade. Okay.

[00:57:38]of the is not soluted. So the reaction mix treating with some mild reducing agents like a rink or dimethile sulfate to form an alien stability isolated lines.

[00:58:07]Cumulative range YouTube configurations dial reaction 4 + 2 reaction mixture compound SN1 that means depend That means SN1 that means 3° 2° 1 more.

[00:59:26]Type of alky subraction branching at alpha carbon substitution at a beta carbon branching upon S12 strong Ob This doesn't work.

[01:00:42]Final carbon double bond alcohol.

[01:01:08]Sanitizer isopropyl alcohol.

[01:01:15]Rubbing alcohol Physical properties.

[01:01:41]Reaction mode instant blindness of carbon guys.

[01:02:14]levels of prepration alcohol carbon dioxide. Sorry.

[01:02:43]Uh, reaction of proteins.

[01:03:06]Bulb reaction of alkine. Hydrogen for hydration.

[01:03:30]R N X R O RX reaction.

[01:04:03]AliEng equal.

[01:04:36]Ru x + Yeah, there was Where is it?

[01:05:26]Because benzene is electron withdrawing group.

[01:05:33]That's why carbon double bond is highly electrode efficient than carbon double bond is more stable.

[01:06:09]Hydraysis of alky nucleophilic addition reaction reduction of carbon compound reduction of alihide Reduction oxidation.

[01:06:58]Reduction of reduction is like sodium and ethanol reaction metal hydide, lithium, aluminium hydide, sodium beride, hydrogen gas in a presence of copper, S2 gas in the presence of nickel.

[01:07:20]structures and uses.

[01:07:29]It has chloride uses as an anesthetics as an propellant for alcohol. Used for a synthesis of C styrene monomer.

[01:07:42]Preparation of ethile cellulose by reaction between cellulose and ethile chloride in dentistry used as a diagnostic agent for a dead tooth. used as a game to encounter sexual ability.

[01:08:03][clears throat] Chloropform CH3 test to identify kone as in demon test to identify kode as a solvent. Solvent for the preparation plus pesticides.

[01:08:31]Grain uh grain permanent rubber industry but starting material tapings criminal uses used by or even murder victim or excellent Dry clean solvent for the depression of fluocarbon.

[01:09:00]Depression solvent for extraction for vegetables oil from plants such as soya, coconut, palm, tetrachlorine.

[01:09:17]Try more ethanol.

[01:09:21]Try more ethanol guys.

[01:09:25]Click solution of pure carbon.

[01:09:40]Solvent for a extraction for vegetable waste from plant such as a soya pop.

[01:09:53]kitchen decrease in the metal part used to prepare 112 most engines dlorin C A C L C name lithyl chloride dth dchlorometer uses it is a volatile and ability to dissolve wide range of nonpolar organic compound so used as a solvent for many chemical process propellant or aerosol to w certain type of plastics iod C H I3 synonym triodom in a small scale. Use as a disinfectant as an antiseptic for to heal and a brising for wound.

[01:11:21]A active ingredient in many ear powder for drug.

[01:11:45]Ethiop alcohol antiseptic most commonly antibacterial available in the form of a hand sanitizer unit take the poison of your medicinal solvent in a engine fuel in a perfume and deodorant laptop.

[01:12:38]solvent preparation of formally acidic acid derivative of as a dead fuel but one C cl3 C3 Antibacterial antifungal 0.05% 05% mix with H2 or as a preservative weak and local anesthetic sedative and a hypnotic cytoine alcohol use viscosity increasing. It is called fatty alcohol used as an imulsion stabilizer surfectant in a hair product for hair conditioning.

[01:13:45]Then the alcohol screen uses use as a um 5% in a treatment of a head life as a preservative in allow concentration in IV medication and cosmetic depression insect. Acid in a high concentration for benzilation in a chemical reaction.

[01:14:18]Glycerol glycerin food industry sweetener and preservative as a ingredient to provide smoothness.

[01:14:42]to reduce itching in the arction ecigarette to create smokey smooth environment.

[01:14:54]Two, prepare active medications such as nitroglycerin teen glycol. propylene glycol uses alcohol based hand sanitizer.

[01:15:13]You may turn used in a various edible item such as coffee related drinks, liquid sweetener and sometimes in ice cream to preserve it and DNA after the break.

[01:15:58]Thank you.

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