The potassium permanganate test distinguishes unsaturated hydrocarbons (alkenes) from saturated hydrocarbons: when 1% potassium permanganate solution is added to an alkene, the purple color disappears and a brown manganese dioxide precipitate forms as the alkene is oxidized to a diol, while saturated hydrocarbons show no reaction and retain the purple color.
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ORGANIC CHEMISTRY Functional Group ID Analysis: Test for Alkenes- PermanganateAdded:
Here is 1% potassium permanganate, which will be used to test two compounds in these two test tubes, where the control test tube will contain a saturated hydrocarbon, and the sample test tube will contain an unsaturated hydrocarbon.
Each test tube gets about 2 ml of solution.
Now, an equal volume of a dilute 1% potassium permanganate solution is added to each test tube.
The control test tube remains purple in the bottom layer, indicating a negative test because saturated hydrocarbons do not react with potassium permanganate under these conditions.
In the sample test tube, the purple color disappears and a brown precipitate forms.
The positive test confirms the presence of an alkene, which is oxidized to a diol, while the permanganate ion is reduced to manganese dioxide, observed as the brown solid precipitate.
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